I'm going to quote this article directly from the post at popsci.typepad.com, because this is the second post of the day and I'm too lazy to write out another full post. From popsci.typepad.com article "The Amazing Rusting Aluminum":
Quote,
Findings: Rust can hold an airplane together or dissolve it to bits.
Element: Aluminum
Project: Destroying it
Time: 1 hour
Dabbler | | | | | Master
"Unless you are a representative of a national meteorological bureau
licensed to carry a barometer (and odds are you’re not), bringing
mercury onboard an airplane is strictly forbidden. Why? If it got
loose, it could rust the plane to pieces before it had a chance to
land. You see, airplanes are made of
aluminum, and aluminum is highly unstable.
"Wait, isn’t one of the great things about aluminum that,
unlike iron, it doesn’t rust? Am I talking about the same aluminum?
Yes! Your aluminum pot is made of a highly reactive chemical. It simply
has a trick that lets it disguise itself as a corrosion-resistant
metal.
"When iron rusts, it forms iron oxide—a reddish, powdery
substance that quickly flakes off to expose fresh metal, which
immediately begins to rust, and so on until your muffler falls off.
"But when aluminum rusts, it forms aluminum oxide, an entirely
different animal. In crystal form, aluminum oxide is called corundum,
sapphire or ruby (depending on the color), and it is among the hardest
substances known. If you wanted to design a strong, scratchproof
coating to put on a metal, few things other than diamond would be
better than aluminum oxide.
"By rusting, aluminum is forming a protective coating that’s
chemically identical to sapphire—transparent, impervious to air and
many chemicals, and able to protect the surface from further rusting:
As soon as a microscopically thin layer has formed, the rusting stops.
(“Anodized” aluminum has been treated with acid and electricity to
force it to grow an extra-thick layer of rust, because the more you
have on the surface, the stronger and more scratch-resistant it is.)
"This invisible barrier forms so quickly that aluminum seems,
even in molten form, to be an inert metal. But this illusion can be
shattered with aluminum’s archenemy, mercury.
"Applied to aluminum’s surface, mercury will infiltrate the
metal and disrupt its protective coating, allowing it to “rust” (in the
more destructive sense) continuously by preventing a new layer of oxide
from forming. The aluminum I-beam below rusted half away in a few
hours, something that would have taken an iron beam years.
"I’ve heard that during World War II, commandos were sent deep
into German territory to smear mercury paste on aircraft to make them
inexplicably fall apart. Whether the story is true or not, the sabotage
would have worked. The few-micron-thick layer of aluminum oxide is the
only thing holding an airplane together. Think about that the next time
you’re flying. Or maybe it’s better if you don’t."
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